Amino Acids, Peptides and Proteins: A Review of the by R C Sheppard

By R C Sheppard

This product isn't really to be had individually, it is just bought as a part of a collection. There are 750 items within the set and those are all offered as one entity, expert Periodical studies supply systematic and special overview insurance of growth within the significant parts of chemical study. Written through specialists of their professional fields the sequence creates a distinct carrier for the lively study chemist, offering standard severe in-depth bills of growth specifically components of chemistry. For over eighty years the Royal Society of Chemistry and its predecessor, the Chemical Society, were publishing reviews charting advancements in chemistry, which initially took the shape of Annual reviews. although, via 1967 the full spectrum of chemistry may now not be contained inside one quantity and the sequence professional Periodical experiences used to be born. the once a year studies themselves nonetheless existed yet have been divided into , and for this reason 3, volumes overlaying Inorganic, natural and actual Chemistry. For extra normal insurance of the highlights in chemistry they continue to be a 'must'. for the reason that that point the SPR sequence has altered in accordance with the fluctuating measure of job in numerous fields of chemistry. a few titles have remained unchanged, whereas others have altered their emphasis in addition to their titles; a few were mixed below a brand new identify while others have needed to be discontinued. the present checklist of professional Periodical experiences should be noticeable at the inside of flap of this quantity learn more... summary: This product isn't really to be had individually, it's only bought as a part of a collection. There are 750 items within the set and those are all offered as one entity, professional Periodical reviews offer systematic and designated overview assurance of development within the significant components of chemical learn. Written by means of specialists of their professional fields the sequence creates a different carrier for the lively examine chemist, providing commonplace severe in-depth bills of growth particularly components of chemistry. For over eighty years the Royal Society of Chemistry and its predecessor, the Chemical Society, were publishing stories charting advancements in chemistry, which initially took the shape of Annual reviews. although, through 1967 the total spectrum of chemistry might now not be contained inside of one quantity and the sequence professional Periodical stories was once born. the yearly studies themselves nonetheless existed yet have been divided into , and to that end 3, volumes overlaying Inorganic, natural and actual Chemistry. For extra basic insurance of the highlights in chemistry they continue to be a 'must'. due to the fact that point the SPR sequence has altered in response to the fluctuating measure of job in a variety of fields of chemistry. a few titles have remained unchanged, whereas others have altered their emphasis in addition to their titles; a few were mixed lower than a brand new identify while others have needed to be discontinued. the present record of expert Periodical experiences may be visible at the within flap of this quantity

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Additional resources for Amino Acids, Peptides and Proteins: A Review of the Literature (Specialist Periodical Reports) (Vol 12)

Sample text

A study of the nitrosation of functional groups in the protein amino-acids, other than the a-amino-group, has been fully described;286aqueous acetic acid solutions of N-acetylcysteine methyl ester to which NaNO, is added yield the corresponding cystine derivative via the thionitrite, while the tyrosine analogue gives a mixture of 3-nitro- and 3-nitroso-derivatives. N-Acetyl-histidine methyl ester and the methionine analogue are not nitrosated under these conditions, but only in more highly acidic media.

C. Bondy and M . E. Harrington, Science, 1979, 203, 1243. '"I A. Jackson, Science, 1979, 206, 483; Science, Chem. , 1971, 7 , 295. ' M 2 T. S. C. Bond y, Science, 1979, 206, 484. ls3 D. Wellner, Science; 1979, 206, 484. I" C. D. Tran and J . H. Fendler, J. A m . Chem. Soc.. 1979, 101, 1285. Tennakone, Prog. Theor. , 1979, 62, 841. K. A. :satyshur and S. T. , 1979, B35, 2260. In' C. Derricott and J . , 1979, 835, 2230. "" Cody, D. A. Langs, and J. P. Hazel, Actu Crystullogr.. 1979, 835, 1829. I A.

A. Bonner, N. E. Blair, and R. M. Lemrnon, J. Am. Chern. , 1979, 101, 1049. "". 8% racemization as well as ca. 256 Racemization of amino-acids via Schiff-base formation in the presence of metal ions is a well known phenomenon. The role of Zn2+ ions in the racemization of Lalanine in media containing pyruvic acid is to stabilize the Schiff base since Zn2+ ions alone do not promote racemization of this amino-acid at pH 210 and at < 80 "C. 259 The mechanism of the direct exchange racemization of cysteine derivatives, involving the p-heteroatom, has been investigated further,260supporting the view that electronic factors determine the rate of base-catalysed racemization through a series of cysteine analogues.

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